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Questa Cmap, creata con IHMC CmapTools, contiene informazioni relative a: Alchools_ini, Physical properties typical as polarity, reaction with alkali metals develops alkoxyde ions RO¯, by products (alkenes) from E2 elimination ????, Chemical behaviour characterized by substitutions, alkoxyde ions RO¯ substitutes an halogenide ion (X¯) in R'-X primary substrate in Williamson's Sn2 reaction, R'-X primary substrate in Williamson's Sn2 reaction, reactions of elimination of water helped by acids and high temp., ALCHOOLS have structure R-O-H, structure R-O-H can be primary -R-CH2OH, Sn1 reactions with X¯ and HX impossible with primary alchools, halogenides via substitution Sn2 with hydroxyde ions (OH¯), Chemical behaviour characterized by amphoterism similar to water, intermolecular H-bonds cause higher boiling point, Physical properties typical as intermolecular H-bonds, oxidation reaction impossible without breaking C-C bonds in tertiary alchool, electrophylic addition of water can be hydroboration with 1. BH3 in THF 2. H2O2 in OH¯, reaction with alkali metals develops H2(g), ALCHOOLS are named by prefix- Hydroxy-, carbonylic compounds from primary or secondary alchools i.e. <math xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> <mtext> primary al. R-C </mtext> <mmultiscripts> <mtext> H </mtext> <mtext> 2 </mtext> <none/> </mmultiscripts> <mtext> -OH </mtext> </mrow> </math>, simple acid catalyzed give more substituted alchool