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This Concept Map, created with IHMC CmapTools, has information related to: amines, electrophile in Aromatic Electrophilic Substitutions of Ar-H atom. called copulation, nucleophiles as in ammonia alkylation, amines can be derived from ammonia alkylation, 1, 2, 3 Hydrogens by alkyls or aryls giving primary amines R-NH2, 1, 2, 3 Hydrogens by alkyls or aryls giving tertiary amines RR'R"N, <math xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> <mtext> Ar-N= </mtext> <mmultiscripts> <mtext> N </mtext> <none/> <mtext> + </mtext> </mmultiscripts> </mrow> </math> reacts as a electrophile in Aromatic Electrophilic Substitutions of Ar-H atom., ammonia alkylation generates mixtures of amines Iª, IIª, IIIª and quaternary ammonium, <math xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> <mtext> Ar-N= </mtext> <mmultiscripts> <mtext> N </mtext> <none/> <mtext> + </mtext> </mmultiscripts> </mrow> </math> reacts as a Substrate of Aromatic Nucleophilic Substitution, amines are trivalent, reduced nitrogen derivatives, Ar-N=N-Ar or diazocompounds used as stains, amines are more basic, <math xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> <mtext> Ar-N= </mtext> <mmultiscripts> <mtext> N </mtext> <none/> <mtext> + </mtext> </mmultiscripts> </mrow> </math> stable only below 5 °C, amines can be derived from amides, Cl¯, Br¯, I¯, CN¯ F¯ from HBF4, H¯ from H3PO2 OH¯ from water as nucleophiles to form Ar-Cl, Ar-Br, Ar-CN, Ar-I, Ar-F, Arenes, phenoles, more basic than ammonia, amines can be derived from carbonylic compounds, Substrate of Aromatic Nucleophilic Substitution attacked by Cl¯, Br¯, I¯, CN¯ F¯ from HBF4, H¯ from H3PO2 OH¯ from water as nucleophiles, electrophile in Aromatic Electrophilic Substitutions of Ar-H atom. generates Ar-N=N-Ar or diazocompounds, diazotation gives <math xmlns="http://www.w3.org/1998/Math/MathML"> <mrow> <mtext> Ar-N= </mtext> <mmultiscripts> <mtext> N </mtext> <none/> <mtext> + </mtext> </mmultiscripts> </mrow> </math>, electrophile in Aromatic Electrophilic Substitutions of Ar-H atom. requires an activated aromatic nucleus